AlkoxyFunctionalized ThienylVinylene Polymers for FieldEffect Transistors and AllPolymer Solar Cells
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چکیده
In the last decade, π-conjugated polymeric materials have emerged as promising semiconductors for low-cost organic optoelectronic applications, such as organic thin-fi lm transistors (OTFTs) [ 1 ] and photovoltaics (OPVs) [ 2 ] to cite two device categories. Planar π-conjugated building blocks represent a key target for highperformance polymeric semiconductors, since π-system planarization facilitates π-electron delocalization and charge transport. [ 3 ] Furthermore, coplanar geometries and structure rigidifi cation can suppress rotational disorder about single bonds and lower Marcus reorganization energies, both of which enhance carrier mobility. [ 4 ]
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تاریخ انتشار 2014